Cleaning article containing hydrophilic polymers

ABSTRACT

The invention relates to a cloth that can function as a moisturizing cleanser. When the cloth is moistened with water, it works up into a warm, sudsy cleansing lotion that feels great and works well as a facial cleansing cloth. The cloth contains water, at least one surfactant and at least one hydrophilic polymer.

RELATED APPLICATIONS

This application is a divisional application of Ser. No. 11/008,679,filed Dec. 4, 2004, now U.S. Pat. No. 7,332,224 B2, which is adivisional application of Ser. No. 10/293,812, filed Nov. 13, 2002, nowU.S. Pat. No. 6,846,480 B2, issued Jan. 25, 2005, which claims benefitto provisional application Ser. No. 60/337,512 filed Dec. 7, 2001 whichis incorporated by reference in its entirety for all useful purposes.

FIELD OF THE INVENTION

The invention relates to a cloth that can function as a moisturizingcleanser. When the cloth is moistened with water, it works up into awarm, sudsy cleansing lotion that feels great and works well as a facialcleansing cloth.

BACKGROUND OF THE INVENTION

The problems encountered in producing foam-based sheets or pads designedto meet household cleaning needs have been addressed by a variety ofproducts. Polyurethane foam-based sponge products which have beendisclosed fall into two general classes, which may be designated as dryand moist. Dry sponge products are disclosed by Strickman et al in U.S.Pat. Nos. 4,271,272 and 4,421,526. These products are formed by reactingisocyanate-capped polypropylene glycol resins with small amounts ofwater and organic catalysts, followed by stirring powdered detergentsand/or abrasives into the foaming resin. Since the molar ratio of waterto free isocyanate groups on the resin is generally adjusted to about0.5 or less, the cured foam which is obtained is dry. This results inadditives such as abrasives and detergents being largely deposited inthe cell voids, thus reducing the sponge's absorbency. When the spongesare remoistened, the additives must re-emulsify prior to becomingavailable for application in a cleaning operation.

Other dry water activated delivery system are described in U.S. Pat.Nos. 6,001,380 and 5,538,732.

The preparation of open-called, hydrophilic or “moist” polyurethanefoams by the reaction of specially-formulated prepolymer isocyanateresins with large molar excesses of water without the need for addedcatalysts or cross-linking agents is disclosed in U.S. Pat. Nos.3,890,254; 4,137,200 and 4,160,076. These resins permit the introductionof large amounts of solids into the form matrices via preformed aqueousslurries of solid particles which are subsequently reacted with theprepolymer resin in order to foam it into the desired specialty product.The finished foams are very hydrophilic, or water-absorbent, due to theentrapment of excess water within the cell walls.

U.S. Pat. Nos. 3,833,386; 4,066,394; 4,066,578; 4,309,509; and 3,343,910describe the incorporation into hydrophilic forms of sinterable ceramicmaterials, water-softening minerals such as zeolites, flame retardants,ordorant-containing waxes and fine abrasives, respectively. In order toproduce solids-loaded foams for use as polishing pads, sachets,water-softening sponges, cushions and the like, the weight ratio ofaqueous phase to resin must be maintained at a value low enough so thatthe foam matrix exhibits satisfactory overall integrity. Increasing theweight of additives in foamed products formed by this method necessarilyrequires the use of higher ratios of water to prepolymer resin, which inturn attenuates the polymeric cellular matrix which is furtherembrittled by the introduction of the solids. Surfactants which resultin a highly reticulated, open-celled matrix also reduce the absolutestrength of the foam due to the removal of cell window membranes.Although reticulated, open-celled, hydrophilic polyurethane foams whichare highly loaded with particulate abrasives are desirable due to theiroptimal cleaning power, when the weight ratio of dispersed abrasives inthe aqueous phase to the presently-available prepolymer resins exceeds acertain value, the resultant foams will become friable. These foams areunsuitable for use as cleaning pads and sheets due to their low tensilestrength which causes the cured foams to flake or crumble during use.

U.S. Pat. No. 4,581,287 describes the use of foam-textile cleaning pads.

U.S. Pat. No. 5,53,732 (“'732 patent”) discloses a medicated applicatorsheet for topical delivery for skin diseases, such as acne. A flexiblebase sheet is impregnated with impregnated with first and second solidor semi-solid compositions comprising first and second dermatologicalagents, each confined to first and second discrete areas, respectively.The compositions are preferably anhydrous. However, the examples showthe water can be added. The '732 patent does not teach using ahydrophilic polymer.

The following United States patents are assigned to The Procter & GambleCompany and are directed to personal care compositions: U.S. Pat. Nos.6,303,119; 6,280,757; 6,267,975; 6,190,678 and 6,153,208 which are allincorporated by reference in their entirety for all useful purposes.

SUMMARY OF THE INVENTION

Thus, it is an object of the present invention to provide cleaning padsor sheets comprising a hydrophilic polymer, water and at least onesurfactant.

It is another object of the present invention to provide resilientcleaning pads or sheets suitable for cleaning a wide variety ofsurfaces.

Another aspect of the invention is as follows: formulating a goodquality aqueous facial cleansing system, (1) adding at least onesurfactant, (2) water and then combining this aqueous phase with (2) ahydrophilic polymer such as a polyurethane prepolymer. Other hydrophilicpolymers or combination of polymers can be used. Optionally, otheringredients, such as organic or inorganic fillers, abrasives,moisturizers, detergents, fragrances, etc. can be added to the aqueousphase. The resultant reaction mixture is coated on a material, such as apaper, fabric or flexible foam. The final sheet becomes a flexiblepolymeric film, dried, cut into desired sizes and packaged.

Depending on the amount of polymer in the system, there can be a moistready to use skin care product (that could be considered remoistened) orone, as in the case described above, that contains low levels of waterthat is subsequently dried off as described above. The resultant coatedsheet is easily activated by wetting with water forming a rich, sudsycleansing system on a wash cloth.

An important aspect of the invention is the use of a film formingpolymer and in particular, a hydrophilic polyurethane polymer. It allowsthe following: (1) the ability to provide much higher levels ofsurfactants and moisturizes for coating on substrates, (2) the abilityto include (organic or inorganic) fillers that can be attached into thepolymer chain by using organosilanes or not. The fillers can be abrasivefor a deeper skin cleaning capability or short fibers for increased timerelease activity of the active ingredients, (3) the ability to absorbwater without dissolving itself during the cleaning step, and (4)providing integrity to the sheet or pad, which would enable the use ofvery light weight nonwoven or paper materials.

Furthermore, it is feasible to use other hydrophilic polymers that woulddissolve or solubilize with water when moistened. They could contain thesame high levels of surfactants as well.

The objects of the present invention are accomplished by a film madewithout the use of foam or the requirement to be a foam material. Inaddition, the cleansing sheet does not require the use of an enzyme,such as Protease G enzyme which is required in U.S. Pat. No. 6,303,119.This enzyme can be excluded from this invention. The film coating doesnot require and can be made without a foam coupling agent being present.Other objects and advantages of the present invention will becomeapparent from the following description and appended claims.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 illustrates a process to make the sheet according to theinvention.

DETAILED DESCRIPTION OF THE INVENTION

The composite cleaning pads or sheets of the present invention areprepared by a process comprising forming an aqueous slurry whichincludes a hydrophilic polymer, at least one surfactant and water.

FIG. 1 illustrates the preferred technique to make the coated fabric.Water, at least one surfactant and a hydrophilic polymer are mixedtogether in a mixer 22 to form a wet mixture 20. As the wet mixture 20comes out of the mix head, it is rolled in between rollers 24 forimpregnating into the sheet 26 as a cleansing film or cleaning sheet 28rather than the traditional hydrophilic foam. The film is dried by anyconventional means such as in an oven. After the film is dried, the filmis then processed into sheets as disposable wash cloths.

Sheet

The textile sheet is preferably, a nonwoven. The non-woven can also bewhat is called “apertured”—in other words, there are uniform spaces thatgo right through the nonwoven and made with water jets (apparently thereare several suppliers that produce this type of fabric) usingspecialized equipment. The skin care coating is on each strand ofnonwoven and not in the voids. However, non-apertured nonwovens can alsobe used.

The textile sheet may be selected from any of the natural or synthetic,woven or nonwoven fabrics which posses sufficient hydrophilicity toremain firmly bonded to the layer during use and which posses sufficienttensile strength to prevent the sheet from cracking or separating duringuse. A preferred nonwoven fabric comprises a polyester/rayon blend, mostpreferably a 70-80% polyester, 20-30% rayon blend such as are availablefrom Precision Custom Coatings in weights of about 1.0-5.0 oz./yd.Multi-ply textiles may be employed, thus allowing the preparation ofcleaners in which the thickness of the cloth portion is equal to orexceeds that of the sheet.

The hydrophilic polyurethane coating can be easily applied to thetraditional nonwoven fabrics as a total overcoat or applied in a varietyof patterns. Coatings can be applied to paper, urethane foams, etc. justas well.

Formulations

The composition comprises an aqueous composition which contains water,at least one surfactant and at least one hydrophilic polymer. Thecomposition can optionally be combined with fillers, abrasives,moisturizers, detergents, fragrances, etc.

Hydrophilic polymers in combination with other polymers, such aspolysaccharides (chitins, celluloses, modified celluloses, etc.) couldbe especially useful. The polymer film allows thinner, less strongnonwoven fabrics to be used, because the film adds strength and body.

Hydrophilic Polymer

The hydrophilic polymer is present in an amount from 0.01 to 90%,preferably from 1% to 45%, and most preferably from 25 to 35% based onthe total amount of the ingredients present in the slurry. This appliesto other hydrophilic polymers—not just the urethane types.

Commercially available class of water prepolymer resins which yieldcross-linked, hydrophilic polyurethane upon the addition ofstoichiometric excesses of water are those belonging to the Hypol®series (Dow; FHP 3000, 2000, 2000 HD, 2002) which are generallydescribed in U.S. Pat. No. 4,137,200, the disclosure of which isincorporated by reference herein. These liquid resins are prepared bycapping mixtures of low molecular weight polyols having 3-8 hydroxylgroups and polyoxyethylene diols with toluene diisocyanate. The cappedalcohol mixtures have an average number of free isocyanate groups permolecule which is equal to two or more, i.e., 2-8.

These prepolymer resins can be prepared by polymerizing ethylene oxideto yield polyalkylenoxy polyols having a molecular weight of about900-1100. These polyols are reacted with a stoichiometric excess of apolyisocyanate. Suitable isocyanates include toluene diisocyanate,triphenylmethane-4,4′,4″-triisocyanate, benzene-1,3,5-triisocyanate,hexamethylene diisocyanate, xylene diisocyanate, chlorophenylenediisocyanate and mixtures thereof. The useful resins recovered have asomewhat lower number of mEg of free isocyanate groups (NCO) per gram ofresin than do the Hypol® resins, e.g. 1.3-1.5 mEq NCO/gram and exhibit asubstantially higher tensile strength when foamed and cured at ambienttemperatures to incorporate high percentages of dispersed abrasives.

One such commercially available self cross-linking resin is Trepol®prepolymer resin (Rynel, Boothbay, Me.), which forms acceptable foamsupon reaction with at least a stoichiometric excess of water withoutemploying a low molecular weight polyol component to raise the averagenumber of free isocyanate groups per glycol ether molecule to above two.TRE STD®. resin has an average free isocyanate content of about 1.4mEq./gram, comprises a polyol component having an average molecularweight of about 1000, exhibits a viscosity at 32° C. of 4700 cps andsolidifies at 15.5° C.

The preferred hydrophilic polymer is polyurethane polymer used in thepreferred system is one made by Rynel, of Boothbay, Me. called Trepol®.It has a rather low NCO content in comparison to other availableurethane prepolymers. It is made with lower concentrations of toluenedi-isocyanate thus providing lower NCO content. The preferred level is30%, but less can be used—possibly down to 10% and as much as 60% on thehigh side.

Other polymers are described in the following U.S. Pat. Nos.

6,277,386,

5,962,620,

5,932,200,

5,728,762,

5,650,225,

5,563,233,

5,334,691,

5,120,816,

5,000,948,

4,963,638,

4,920,172,

4,847,141,

4,828,911,

4,820,577,

4,810,582,

4,810,543,

4,806,598,

4,798,876,

4,789,720,

4,767,825,

4,743,673 and

3,975,350.

Other types of “hydrophilic” polymer films such as

Gantrez polymers such as but not limited to polymethyl vinyl ethermaleic anhydride,

gafquat polymers such as, but not limited to vinylpyrrolidone/quarternized dimethylaminoethylmethacrylate

copolymers, copolymer 845 or 937 which arevinylpyrrolidone/dimethylaminoethylmethacrylate copolymers,

PVP/VA series which are vinylpyrrolidone/vinyl acetate copolymers,

Ganex polymers which are alkylated vinylpyrrolidone polymers,

PVP which is polyvinyl pyrrolidone

Polyethylene glycols,

Polyacrylate copolymers,

PVDC which is polyvinylidene dichloride and combinations thereof.

In addition, combinations of (vinyl acetate, acrylics, etc.), acrylatesthemselves and blends (polyacrylic acid and others), polyvinyl alcohol,etc. that could be used in place of the urethanes or in combination withthe urethanes.

Surfactants

A wide variety of surfactants can be used at levels below 12.5% and evenbelow 10%. Furthermore the surfactants can be at levels as high as about70%. The surfactants can be nonionic, anionic, cationic zwitterionic andamphoteric, types—alone or in combination. Moreover, soap bases (soapbars) such as sodium stearate and similar bases as found in Dove, Dial,etc. can be used.

The total amount of surfactant, which is preferably used is about 0.05to about 90%, most preferably in one embodiment in an amount about 1 toabout 10% by weight of the aqueous phase. The range is preferably from 8to 90% and preferably from 20 to 60% by weight.

Preferred nonionic surfactants include the condensation products ofethylene oxide with a hydrophobic polyoxyalkylene base formed by thecondensation of propylene oxide with propylene glycol. The hydrophobicportion of these compounds has a molecular weight sufficiently high soas to render it water-insoluble. The addition of polyoxyethylenemoieties to this hydrophobic portion increases the water-solubility ofthe molecule as a whole, and the liquid character of the product isretained up to the point where the polyoxyethylene content is about 50%of the total weight of the condensation product.

Examples of compounds of this type include certain of thecommercially-available Pluronic® surfactants (BASF), especially those inwhich the polyoxypropylene ether has a molecular weight of about1500-3000 and the polyoxyethylene content is about 35-55% of themolecule by weight, i.e. Pluronic® L-62.

Other useful nonionic surfactants include the condensation products ofC8-C22 alkyl alcohols with 2-50 moles of ethylene oxide per mole ofalcohol. Examples of compounds of this type include the condensationproducts of C11-C15 secondary alkyl alcohols with 3-50 moles of ethyleneoxide per mole of alcohol which are commercially-available as thePoly-Tergent® SLF series from Olin Chemicals or the Tergitol® seriesfrom Union Carbide, i.e. Tergitol® 25-L-7, which is formed by condensingabout 7 moles of ethylene oxide with a C12-C15 alkanol.

Other nonionic surfactants which may be employed include the ethyleneoxide esters of C6-C12 alkyl phenols such as(nonylphenoxy)polyoxyethylene ether. Particularly useful are the estersprepared by condensing about 8-12 moles of ethylene oxide withnonylphenol, i.e. the Igepal® CO series (GAF Corp., New York, N.Y.).

A further useful class of nonionic surfactant is amine oxides, such asthe C10-C20-alkyl-di(lower)alkyl-amine oxides or theC10-C20-alkylamino(C2-5)alkyl di(lower)alkyl-amine oxides. Especiallypreferred members of this class include lauryl(dimethyl)amine oxide,myristyl(dimethyl)amine oxide, stearyl(dimethyl)amine oxide (Schercamox®DMS, Scher Chemicals, Inc., Clifton, N.J.), coco(bis-hydroxyethyl)amineoxide (Schercamox® CMS), tallow(bis-hydroxyethyl)amine oxide,cocoamidopropyl amine oxide and cocoamidopropyl(dimethyl)amine oxide(Schercamox® C-AA).

Another useful class of nonionic surfactant is the silicone-glycolcopolymers. These surfactants are prepared by addingpoly(lower)alkylenoxy chains to the free hydroxyl groups ofdimethylpolysiloxanols and are available from the Dow Corning Corp asDow Corning 190 and 193 surfactants (CTFA name: dimethicone copolyol.).

Other useful nonionics include the ethylene oxide esters of alkylmercaptans such as dodecyl mercaptan polyoxyethylene thioether, theethylene oxide esters of fatty acids such as the lauric ester ofpolyethylene glycol and the lauric ester of ethoxypolyethylene glycol,the ethylene oxide ethers of fatty acid amides, the condensationproducts of ethylene oxide with partial fatty acid esters of sorbitolsuch as the lauric ester of sorbitan polyethylene glycol ether, andother similar materials, wherein the mole ratio of ethylene oxide to theacid, phenol, amide or alcohol is about 5-50:1.

Anionic surfactants preferred are described in the examples and due totheir high detergency include anionic detergent salts having alkylsubstituents of 8 to 22 carbon atoms such as the water-soluble higherfatty acid alkali metal soaps, e.g., sodium myristate and sodiumpalmitate. An especially preferred class of anionic surfactantsencompasses the water-soluble sulfated and sulfonated anionic alkalimetal and alkaline earth metal detergent salts containing a hydrophobichigher alkyl moiety (typically containing from about 8 to 22 carbonatoms) such as salts of higher alkyl mono or polynuclear aryl sulfonateshaving from about 1 to 16 carbon atoms in the alkyl group (e.g., sodiumdodecylbenzenesulfonate, magnesium tridecylbenzenesulfonate, lithium orpotassium pentapropylenebenzenesulfonate). These compounds are availableas the Bio-Soft® series, i.e. Bio-Soft D-40 (Stephan Chemical Co.,Northfield, Ill.).

Other useful classes of anionic surfactants include the alkali metalsalts of alkyl naphthalene sulfonic acids (methyl naphthalene sodiumsulfonate, Petro® AA, Petrochemical Corporation); sulfated higher fattyacid monoglycerides such as the sodium salt of the sulfatedmonoglyceride of coconut oil fatty acids and the potassium salt of thesulfated monoglyceride of tallow fatty acids; alkali metal salts ofsulfated fatty alcohols containing from about 10 to 18 carbon atoms(e.g., sodium lauryl sulfate and sodium stearyl sulfate); sodium laurethsulfate; sodium C.sub.14-C.sub.16-alphaolefin sulfonates such as theBio-Terge® series (Stephan Chemical Co®.); alkali metal salts ofsulfated ethyleneoxy fatty alcohols (the sodium or ammonium sulfates ofthe condensation products of about 3 moles of ethylene oxide with aC.sub.12 14 C.sub.15 n-alkanol, i.e., the Neodol® ethoxysulfates, ShellChemical Co.); alkali metal salts of higher fatty esters of lowmolecular weight alkylol sulfonic acids, e.g., fatty acid esters of thesodium salt of isethionic acid; the fatty ethanolamide sulfates; thefatty acid amides of amino alkyl sulfonic acids, e.g. lauric acid amideof taurine; as well as numerous other anionic organic surface activeagents such as sodium xylene sulfonate, sodium naphthalene sulfonate,sodium toluene sulfonate and mixtures thereof.

A further useful class of anionic surfactants includes the8-(4-n-alkyl-2-cyclohexenyl)-octanoic acids wherein the cyclohexenylring is substituted with an additional carboxylic acid group. Thesecompounds, or their potassium salts, are commercially-available fromWestvaco Corporation as Diacid® 1550 or H-240.

Other surfactants are described in U.S. Pat. Nos. 6,133,212; and6,191,083 which are incorporated by reference for all useful purposes intheir entireties.

Water

The last of the required ingredients is water. Water is present in anamount from 10% to about 85% and preferably from 20% to about 60% basedon the total amount of the ingredients present in the slurry.

Optional Ingredients

Fillers

Fillers, such as inorganic or organic fillers can be used. The fillersallow a controlled release of actives (such as surfactants,moisturizers, etc.) from the hydrophilic polyurethane film, as the filmabsorbs water when wetted.

Organic fillers useful in the practice of the present invention includecarboxymethylcellulose, polyvinylpyrrolidone and polymeric organicwaxes. The useful polymeric waxes include ethylene acrylate copolymers,ethylene acrylic acid copolymers, and polyethylene (e.g. oxidizedpolyethylenes). These materials are commercially available in the formof aqueous emulsions or dispersions, e.g. from Allied-Signal,Morristown, N.J., as the A-C Copolymer and A-C Polyethylene series, suchas A-C Copolymer 540, A-C Copolymer 580 and A-C Polyethylene 617 and629.

Preferably, the inorganic fillers employed will comprise those ofnatural or synthetic of mineral origin. One preferred inorganic filleris diatomaceous earth. Other fillers are the smectite clays such as thesaponites colerainites, and sapphires and the montmorillonite colloidalclays (magnesium aluminum silicate) such as Veegum® (VanderbiltMinerals, Murray, Ky.) or Magnabrite® (American, Colloid Co., Skokie,Ill.). Modified magnesium aluminium silicate materials such as magnesiumaluminium silicate mineral/CMC are available from the R.T VanderbiltCompany, Inc. under the trade name Veegum Plus®. This modified claymaterial contains smectite clay with sodium carboxymethylcellulose andtitanium dioxide. Bentonite is a native hydrated colloidal aluminiumsilicate clay available from ECC America under the trade name BentoniteH (RATM) and from Whittaker, Clark and Daniels under the trade nameMineral Colloid BP 2430®. Hectorite is one of the montmorilloniteminerals that is a principal constituent of bentonite clay. Hectorite isavailable from Rheox Inc. under the trade names Bentone EW® andMacaloid®.

Synthetic sodium magnesium silicate clays and fumed silicas can also beused as fillers.

In addition, silicates can also be used, alone or in combination withthe clays to produce fine open-celled foams. Preferred inorganicsilicates are the naturally-occurring calcium metasilicates such aswollastonite, available as the NYAD® wollastonite series (ProcessedMinerals Inc., Willsboro, N.Y.), of which NYAD® 400 is especiallypreferred.

The filler is preferably is used in amounts from about 1.0% to about60%, and more preferably from about 4.0% to about 25% based on the totalamount of the ingredients present in the slurry.

Abrasives

There can optionally be an abrasive material. The choice of abrasivematerial may be made from a wide variety of materials of adequatehardness and of a particle size range which will enable them toeffectively scour soiled surfaces.

Preferably, the weight of the abrasive used will be from about 0.25% ofthe prepolymer weight, most preferably 10%.

A preferred abrasive for use in the present invention is (AluminiumOxide) available from Degussa Corporation, Parsippany, N.J. Among thesubstances that meet this requirement are minerals such as thefeldspars, quartz, aluminas, diatomaceous earths, sands, glasses,naturally-occurring and synthetic zeolites, zircon, carborundum, pumiceand the like, which may be used singly or in mixtures.

Moisturizers

Moisturizers can be added to the formula. In preferred embodiments, themoisturizer is selected from:

1. water-soluble liquid polyols;

2. essential amino acid compounds found naturally occurring in thestratum corneum of the skin; and

3. water-soluble nonpolyol nonocclusives and mixtures thereof.

Some examples of more preferred nonocclusive moisturizers are glycerine,polyethylene glycol, propylene glycol, sorbitol, polyethylene glycol andpropylene glycol ethers of methyl glucose (e.g. methyl glucam E-20),polyethylene glycol and propylene glycol ethers of lanolin alcohol (e.g.Solulan-75), sodium pyrrolidone carboxylic acid, lactic acid, urea,L-proline, guanidine, pyrrolidone, hydrolyzed protein and othercollagen-derived proteins, aloe vera gel, acetamide MEA and lactamideMEA and mixtures thereof. Of the above, examples of moisturizers arePEG-7 glyceryl cocoate and PEG-10 soya sterol. Another preferredmoisturizer is Finsolv TN which is an alkylbenzoate.

The preferred level of such moisturizers is from about 0.05% to about15% by weight, preferably between 0.5% to about 10% by weight based onthe total amount of the ingredients present in the slurry.

Some examples of more preferred nonocclusive moisturizers arepolybutene, squalane, sodium pyrrolidone carboxylic acid, D-panthenol,lactic acid, L-proline, guanidine, pyrrolidone, hydrolyzed protein andother collagen-derived proteins, aloe vera gel, acetamide MEA andlactamide MEA and mixtures thereof.

Detergents

Amphoteric detergents may also be incorporated into these hydrophilicpolymers. These detergents can be employed in a compatible proportionand manner with the nonionic-anionic surfactants, and may comprise about0.05-10%, preferably 1-5% of the aqueous phase.

Examples of amphoteric detergents which may be employed include thefatty imidazolines, such as2-coco-1-hydroxyethyl-1-carboxymethyl-1-hydroxyl-imidazoline and similarproducts made by reacting monocarboxylic fatty acids having chainlengths of 10-24 carbon atoms with 2-hydroxyethyl ethylene diamine andwith monohalo monocarboxylic fatty acids having from 2 to 6 carbonatoms; the fatty beta-alanines such as dodecyl beta-alanine, the innersalt of 2-trimethylamino lauric acid, and betaines such asN-dodecyl-N,N-dimethylamino acetic acid and the like.

Fragrances

Minor, but effective amount of fragrance selected so as to bechemically-compatible with the above-described surfactants arepreferably included in the aqueous phase for cosmetic purposes. Usefulfragrances will include, for instance about 0.025-2%, preferably about0.05-1.5% of floral oils such as rose oil, lilac, jasmine, wisteria,lemon, apple blossom, or compounds bouquets such as spice, aldehydic,woody, oriental, and the like.

Other Optional Ingredients

Minor amounts of other adjuvants, such as dyes, flame retardants and thelike, may be introduced into the present products in effective amountseither via the aqueous or resin phase or by treating the final productwith the adjuvants as by spraying, mixing, etc. Other optionalingredients include topical dermatological drug ingredients that couldbe useful such as antihistamines, antibiotics, antifungal agents,sunscreen agents, etc. anti-acne drugs, corticosteroids likebetamethasone dipropionate, fluocinide, etc.

Emollient esters, mineral oils, silicone and other solvents can beincorporated into the polymer film for release. These items can beencapsulated or just added as a liquid phase ingredient. Naturalingredients can be used such as avocado oil, vitamins, such as A, C orE, natural plant emollients, or natural cleansing agents etc.Fragrances, anti-bacterial agents and topical drug ingredients (certaintypes) could be incorporated too.

The samples are coated (100% coverage) on 55 GSM Spunlace Blendnon-woven fabric. The active ingredients were coated on the nonwovenusing a Meyer rod, which coats the total surface (like a doctor blade).A printing technique for the application of the active ingredients thatwould give better control the amount of ingredients necessary to do thejob and it will improve the appearance.

These samples truly function as a moisturizing cleanser. When the clothis moistened with water, it works up into a warm, sudsy cleansing lotionthat feels great. Preferably, is a light, fresh fragrance is used. Thiscan be changed relatively easily if it is not acceptable to the user.

The invention will be further described by reference to the followingdetailed examples.

In Example 1, the following ingredients were mixed together, water,Sodium laureth sulfate (50% active), Cocoamidopropyl amine oxide (30%active), PEG-7 glyceryl cocoate, PEG-10 soya sterol, Diatomaceous earthand Hydrophilic polyurethane prepolymer to form a aqueous slurry. Theaqueous slurry was coated on a textile material. The formulation isdescribed in Table 1 below:

TABLE 1 New Water Activated Dry Cleansing Cloth Dried Film % SolidsIngredients Formula % Solids in Film Water 4.00 2.50 3.57 Sodium laurethsulfate 50.00 25.00 35.71 (50% active) Cocoamidopropyl amine 5.00 1.501.05 oxide (30% active) PEG-7 glyceryl cocoate 2.00 2.00 2.86 PEG-10soya sterol 2.00 2.00 2.86 Diatomaceous earth 7.00 7.00 10.00Hydrophilic polyurethane 30.00 30.00 42.86 prepolymer 100.00 70.00100.00 Components in Substrate 2.5 grams Coating (2 g.) Coating 2.0grams Water 0.0714 Total 4.5 grams Surfactants 0.7352 Moisturizers0.1144 Filler 0.2000 Polymer 0.8572 Total □2.0 g. 0.7352/2.5 g. = 29%surfactant based on weight of nonwoven 0.7352/3.36 g = 18.81% surfactantbased on weight of nonwoven + polymer

The textile sheet performs the dual function of reinforcing the sheetand providing a nonabrasive cleaning and wiping surface on the pad. Whenmoistened, these double-surfaced pads are useful for cleaning a widevariety of porous and nonporous household or workplace surfaces, such ascountertops, appliances or bathroom fixtures, including surfaces formedof wood, linoleum, metal, porcelain, glass, plastics or ceramics. At lowlevels of polymer and high water content of the aqueous phase, apremoistened ready to use skin cleansing system is apparent. In anycase, additional water could be added to the final cloths and then usedas a ready to use product.

Additional formulations are shown in the following tables:

TABLE 2 Aqueous-Phase Detergent Formulations - Nanofoam FilmsFormulations reacted with hydrophilic polyurethane pre-polymers & coatedon nonwoven % Ingredients Ingredients 1 2 3 4 5 6 7 8 9 10 Water 35.0735.07 35.07 35.07 35.05 0 35.07 35.07 35.07 35.07 Standapol ES-350 41.090 16.44 20.54 36.98 0 0 0 0 32.87 Standapol LF 0 41.09 24.65 20.54 4.110 0 0 0 8.22 Standapol ES-3 0 0 0 0 0 76.16 0 0 0 0 Sulfatex NL-60 0 0 00 0 0 41.09 0 0 0 Standapol EA-40 0 0 0 0 0 0 0 41.09 0 0 StandapolES-40 0 0 0 0 0 0 0 0 41.09 0 Velvatex BA-35 5.48 5.48 5.48 5.48 5.485.48 5.48 5.48 5.48 5.48 Cetiol HE 6.85 6.85 6.85 6.85 6.85 6.85 6.856.85 6.85 6.85 Celite SFSF 10.96 10.96 10.96 10.96 10.96 10.96 10.9610.96 10.96 10.96 TZ-37 0.41 0.41 0.41 0.41 0.41 0.41 0.41 0.41 0.410.41 Kathon CB 0.14 0.14 0.14 0.14 0.14 0.14 0.14 0.14 0.14 0.14 100 100100 100 100 100 100 100 100 100 OK Too OK Good Good Too Gelled GelledGel Very thick thick good Final Formulations Coated on Nonwoven Aqueousphase 70.00% Rynel Trepol ® prepolymer 30.00% Notes: Coated samples #4and #10 appeared to be best. Coating was approximately 3 grams per 6 ×7″ sheet

TABLE 3 Hydrophilic Polyurethane Nanofoam Film Formulations EvaluationOf “Betaine” Alternate Materials Ingredients 1 2 3 4 5 Water 36.649236.6492 36.6492 36.6492 31.0140 Steol CS-370 20.5380 20.5380 20.538020.5380 0 Rhodapex PS-603 0 0 0 0 11.9840 Standapol LF 0 0 0 0 14.3780Cetilol HE 0.7000 0.7000 0.7000 0.7000 0.7000 Velvatex BA-35 0 0 0 03.8600 Crodsultaine C-50 3.8360 0 0 0 0 Crodasinic LS-30 0 3.8360 0 0 0Macanate LO Special 0 0 3.8360 0 0 Makanate DC-50 0 0 0 3.8360 0 CeliteSFSF 7.6790 7.6790 7.6790 7.6790 7.6790 Fragrance TZ-37 0.2870 0.28700.2870 0.2870 0.2870 Kathon CG 0.0980 0.0980 0.0980 0.0980 0.0980 MethylParaben 0.2030 0.2030 0.2030 0.2030 0 Propyl Paraben 0.0098 0.00980.0098 0.0098 0 Trepol ® Polymer 30.0000 30.0000 30.0000 30.0000 30.0000100 100 100 100 100 Formulations were coated on nonwoven substrate - 2to 3 grams per 6 × 7½″ sheet

TABLE 4 Aqueous Phase Detergent Formulations - Various MoisturizingComponents - Nanofoam Films Formulations reacted with hydrophilicpolyurethane pre-polymer & coated on Nonwoven Ingredients 1 2 3 4 5 6 78 Water 46.486 46.486 46.486 46.486 46.486 46.486 46.486 46.486 SteolCS-370 14.670 14.670 14.670 14.670 14.670 14.670 14.670 14.670 StandapolLF 20.540 20.540 20.540 20.540 20.540 20.540 20.540 20.540 VelvatexBA-35 5.480 5.480 5.480 5.480 5.480 5.480 5.480 5.480 Incrocas 30 1.0000 0 0 0 0 0 0 Procetyl AWS 0 1.000 0 0 0 0 0 0 Glycerox 767 0 0 1.000 00 0 0 0 Dermol 618 0 0 0 1.000 0 0 0 0 Schercemol DISD 0 0 0 0 1.000 0 00 MPDIOL Glycol 0 0 0 0 0 1.000 0 0 Lipocol L-12 0 0 0 0 0 0 1.000 0Crodamol PMP 0 0 0 0 0 0 0 1.000 Celite SFSF 10.970 10.970 10.970 10.97010.970 10.970 10.970 10.970 TZ-37 0.410 0.410 0.410 0.410 0.410 0.4100.410 0.410 Kathon CG 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140Methyl paraben 0.290 0.290 0.290 0.290 0.290 0.290 0.290 0.290 Propylparaben 0.014 0.014 0.014 0.014 0.014 0.014 0.014 0.014 100 100 100 100100 100 100 100 Final formulations coated on nonwoven Aqueous phase70.00% Rynel Trepol ® 30.00% prepolymer

TABLE 5 Aqueous Phase Detergent/Polymer Formulations - CombinationPolymer/Hydrophilic Polyurethane Prepolymer Systems Combination PolymerHydrophilic Polyurethan Film Formulations Composition 1A 2B 3C 4D 5E 6F7G 8H 9I Water 36.862 36.862 30.862 30.862 30.862 30.862 30.862 30.86230.862 Steol CS-370 20.538 20.538 20.538 20.538 20.538 20.538 20.53820.538 20.538 PVP/VA I-335 1.400 0 0 0 0 0 0 0 0 PVP/VA-I-535 0 1.400 00 0 0 0 0 0 PVP/VA I-735 0 0 1.400 0 0 0 0 0 0 PVP/VA W-735 0 0 0 1.4000 0 0 0 0 Copolymer 845 0 0 0 0 1.400 0 0 0 0 Copolymer 937 0 0 0 0 01.400 0 0 0 Stableze QM 0 0 0 0 0 0 1.400 0 0 PVP K-25 0 0 0 0 0 0 01.400 0 Acusol 43OND 0 0 0 0 0 0 0 0 1.400 Velvatex BA-35 3.836 3.8363.836 3.836 3.836 3.836 3.836 3.836 3.836 Celite SFSF 6.979 6.979 6.9796.979 6.979 6.979 6.979 6.979 6.979 TZ-37 0.287 0.287 0.287 0.287 0.2870.287 0.287 0.287 0.287 Kathon CG 0.098 0.098 0.098 0.098 0.098 0.0980.098 0.098 0.098 Trepol ® 30.000 30.000 30.000 30.000 30.000 30.00030.000 30.000 30.000 Prepolymer TOTAL 100 100 100 100 100 100 100 100100

TABLE 6 Non-polyurethane Formulations - Water soluble/Dispersablepolymers Combination Polymer Hydrophilic Polyurethan Film FormulationsComposition 1A 2B 3C 4D 5E 6F 7G 8H 9I Water 52.66 52.66 52.66 52.6652.66 52.66 52.66 52.66 52.66 Steol CS-370 29.34 29.34 29.34 29.34 29.3429.34 29.34 29.34 29.34 PVP/VA I-335 2.00 0 0 0 0 0 0 0 0 PVP/VA-I-535 02.00 0 0 0 0 0 0 0 PVP/VA I-735 0 0 2.00 0 0 0 0 0 0 PVP/VA W-735 0 0 02.00 0 0 0 0 0 Copolymer 845 0 0 0 0 2.00 0 0 0 0 Copolymer 937 0 0 0 00 2.00 0 0 0 Stableze QM 0 0 0 0 0 0 2.00 0 0 PVP K-25 0 0 0 0 0 0 02.00 0 Acusol 43OND 0 0 0 0 0 0 0 0 2.00 Velvatex BA-35 5.48 5.48 5.485.48 5.48 5.48 5.48 5.48 5.48 Celite SFSF 9.97 9.97 9.97 9.97 9.97 9.979.97 9.97 9.97 TZ-37 0.41 0.41 0.41 0.41 0.41 0.41 0.41 0.41 0.41 KathonCG 0.14 0.14 0.14 0.14 0.14 0.14 0.14 0.14 0.14 TOTAL 100 100 100 100100 100 100 100 100

These systems were coated on non-woven substrates and dried in an ovenfor 10 minutes at 160° F. The coating was approximately 2 grams per6″×7.5″ sheet.

Examples of facial wipes are disclosed below. In the examples theassumption is 1.33 square feet per sheet=192 square inches (16″×12″sheet). For moisture loss a Cenco set 50% with initial weights taken at0 time, 5 minutes and 15 minutes. For qualitative flash foam/foamvolumes, 0.20 grams of sheet product into 25 grams distilled water at 30to 35° C. The product was exposed to water for one minute then shakenmanually to a 5 second count.

TABLE 7 Facial wipes Lay- Non- Lay- down Moisture Gross woven downLay-down 6 × 7.5 Initial loss 15 min. % Composition wt. wt. wt. gm/sq ftsheet weight wt loss Sultaine C-50 15.01 6.12 8.89 6.68 2.08 0.99580.9785 1.7 Sarcosinate LS-30 14.27 6.16 8.11 6.10 1.90 0.8550 0.8301 2.9Silicone Sarcosinate DC-50 15.57 5.83 9.74 7.32 2.28 1.1086 1.0885 1.8PVP/VA I-335 13.54 6.25 7.29 5.48 1.71 0.8961 0.8731 2.6 PVP/VA-I-53514.13 6.27 7.86 5.91 1.84 0.8299 0.8028 3.3 PVP/VA I-735 13.32 6.48 6.845.14 1.60 0.9050 0.8817 2.6 PVP/VA W-735 13.98 6.42 7.56 5.68 1.770.8798 0.8575 2.5 Copolymer 845 13.09 6.29 6.80 5.11 1.59 0.8183 0.79732.6 Copolymer 937 13.23 6.45 6.78 5.10 1.59 0.9191 0.8965 2.5 StablezeEZ (no 11.22 6.22 5.00 3.76 1.17 prepolymer) PVP K-25 13.34 6.37 6.975.24 1.63 Acusol 46OND 11.13 6.38 4.75 3.57 1.11 Oil of Olay 0.62280.5960 4.3 Noxema 1.0239 0.9971 2.6 Steol Base 1.0605 1.0482 1.2

One of the embodiments of the invention is again related to a cleansingsystem including hydrophilic polyurethane-filled systems, nanofoam filmsor coatings. The polymer base is water insoluble, but will absorb waterto release active ingredients.

Another embodiment is the combination of polymer systems plushydrophilic polymers, such as polyurethane polymer filled systems. Thecombined polymer base is water insoluble, but will absorb water torelease active ingredients. The combined polymers effect performance offilm (i.e. enhance sudsiness, moisturizing activity etc.)

A still further embodiment is non-polyurethane polymer filled systemswater or non-water soluble films or coatings. The polymer can either betotally water soluble or insoluble, but filled with active ingredientsthan can release with water. The systems can be water based or solventbased.

All of these systems can be coated on a variety of substrates, such asnon-woven, paper, fabric, plastic, foam, etc. Some systems will notrequire a substrate and can be cast into usable durable films that arewater activated.

All the references discussed in this application are incorporated byreference in their entirety for all useful purposes.

While there is shown and described certain specific structures embodyingthe invention, it will be manifest to those skilled in the art thatvarious modifications and rearrangements of the parts may be madewithout departing form the spirit and scope of the underlying inventiveconcept and that the same is not limited to the particular forms hereinshown and described.

1. A method of making a cleaning article comprising the steps of: (a)forming a wet mixture by mixing water, at least one surfactant, ahydrophilic polyurethane polymer and at least one hydrophilicnon-polyurethane polymer selected from the group consisting of monoalkylesters of polymethyl vinyl ether/maleic acid copolymers, quarternizedcopolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate,vinylpyrrolidone/vinyl acetate copolymers, alkylated vinylpyrrolidonepolymers, polyvinyl pyrrolidone, polyethylene glycols, polyacrylatecopolymers, polyvinylidene dichloride, and mixtures thereof; (b)impregnating and/or coating a substrate with the wet mixture in suchmanner that the wet mixture does not form a hydrophilic foam, (c) dryingthe impregnated and/or coated substrate.
 2. The method of claim 1,wherein the cleaning article is impregnated and/or coated with acomposition comprising (a) between about 0.01% and about 90% of acombination of a hydrophilic polyurethane polymer and at least onehydrophilic non-polyurethane polymer; (b) between about 0.05% and about90% of at least one surfactant; and (c) between about 10% and about 85%water, where percentages are based on the total weight of thecomposition.
 3. The method of claim 1, wherein the cleaning article isimpregnated and/or coated with between about 1% and about 45% of acombination of a hydrophilic polyurethane polymer and at least onehydrophilic non-polyurethane polymer polymer; between about 20% andabout 60% of at least one surfactant; between about 20% and about 60%water; and a component selected from the group consisting of organicfillers, inorganic fillers, abrasives, moisturizers, detergents,fragrances, dyes, flame retardants, antihistamines, antibiotics,antifungal agents, sunscreen agents, anti-acne drugs, corticosteroids,and mixtures of these, where percentages are based on the total weightof the wet mixture.
 4. The method of claim 1, wherein the total amountof the combination of hydrophilic polyurethane polymer and at least onehydrophilic non-polyurethane polymer is between about 1% and about 45%,where percentages are based on the total weight of the wet mixture. 5.The method of claim 1, wherein the surfactant is an anionic surfactant,a non-ionic surfactant, or a mixture of both.
 6. The method of claim 1,wherein the surfactant is present in an amount between about 20% andabout 60%, where percentages are based on the total weight of the wetmixture.
 7. The method of claim 1, wherein the water is present in anamount between about 20% and about 60%, where percentages are based onthe total weight of the wet mixture.
 8. The method of claim 1, whereinthe wet mixture further comprises a component selected from the groupconsisting of organic fillers, inorganic fillers, abrasives,moisturizers, detergents, fragrances, dyes, flame retardants,antihistamines, antibiotics, antifungal agents, sunscreen agents,anti-acne drugs, corticosteroids, and mixtures of these.
 9. The methodof claim 1, wherein the wet mixture comprises between about 25% andabout 35% of a combination of a hydrophilic polyurethane polymer and atleast one hydrophilic non-polyurethane polymer selected from the groupconsisting of monoalkyl esters of polymethyl vinyl ether/maleic acidcopolymers, quarternized copolymers of vinylpyrrolidone anddimethylaminoethyl methacrylate, vinylpyrrolidone/vinyl acetatecopolymers, alkylated vinylpyrrolidone polymers, polyvinyl pyrrolidone,polyethylene glycols, polyacrylate copolymers, polyvinylidenedichloride, and mixtures thereof between about 20% and about 60% of atleast one surfactant; between about 20% and about 60% water; and acomponent selected from the group consisting of organic fillers,inorganic fillers, abrasives, moisturizers, detergents, fragrances,dyes, flame retardants, antihistamines, antibiotics, antifungal agents,sunscreen agents, anti-acne drugs, corticosteroids, and mixtures ofthese, where percentages are based on the total weight of the wetmixture.